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41.
《Current Applied Physics》2020,20(5):638-642
A series of bio-silica incorporated barium-ferrite-composites with the composition of (x)Bio-SiO2:(80-x)γ-Fe2O3:(20)BaO, where x = 0, 1, 2, and 3 wt% were prepared using the modified solid-state reaction method. The influence of different bio-silica (extricated from sintered rice husk) contents on the surface morphologies, structures, and magnetic characteristics of these composites were assessed. The relative complex permittivity and permeability were resolved using the Nicholson-Ross-Weir strategy in the frequency range of 8–13 GHz. Meanwhile, the reflection loss was estimated through the transmission/reflection line theory to assess the MW absorption properties of the composites. Incorporation of the bio-silica in the barium ferrite composites generated a new hexagonal phase (Ba3Fe32O51) and a tetragonal phase (BaFeSi4O10) which led to a decrease in the saturation magnetization and significant shift in the MW frequency absorption peak positions. 相似文献
42.
采用超声水浸聚焦斜入射方式进行小棒材表面、近表缺陷检测时,声波在水/棒和棒/缺陷界面会发生反射、折射、散射、衍射及波形转换等一系列物理变换。此时缺陷可检性对声波入射条件十分敏感,常出现由于检测条件设置不当而导致缺陷漏检、误检的情况。为解决这一问题,本文针对小棒材超声斜入射检测中的主要参数——入射角和水距,开展声场及缺陷声响应仿真,研究检测参数对不同部位缺陷检测能力的影响,并对仿真结果进行试验验证。通过研究得到了检测水距、入射角度对缺陷检测能力的影响,并得到最优检测条件。试验验证结果表明研究制定的检测方案可有效检测出表面、近表面裂纹缺陷。 相似文献
43.
In this study lanthanum trilactate was prepared by neutralization reaction of lactic acid and lanthanum oxide, purified and identified by X-ray powder diffraction. Infrared spectra (Mid-IR region 4000–650 cm−1) and Raman spectra (Stokes region 4000–100 cm−1) of the high quality crystalline samples have been recorded and presented for the first time. For comparison DFT calculations were performed using Gaussian 09 D.01 and agreement between predicted and measured spectral data has been achieved. Acquired information can be utilized for substance identification for example in various industrial applications or in biological systems. 相似文献
44.
We give a sheaf theoretic interpretation of Potts models with external magnetic field, in terms of constructible sheaves and their Euler characteristics. We show that the polynomial countability question for the hypersurfaces defined by the vanishing of the partition function is affected by changes in the magnetic field: elementary examples suffice to see non-polynomially countable cases that become polynomially countable after a perturbation of the magnetic field. The same recursive formula for the Grothendieck classes, under edge-doubling operations, holds as in the case without magnetic field, but the closed formulae for specific examples like banana graphs differ in the presence of magnetic field. We give examples of computation of the Euler characteristic with compact support, for the set of real zeros, and find a similar exponential growth with the size of the graph. This can be viewed as a measure of topological and algorithmic complexity. We also consider the computational complexity question for evaluations of the polynomial, and show both tractable and NP-hard examples, using dynamic programming. 相似文献
45.
价廉易得的L-亮氨酸先以苄基同时保护氨基及羧基得(S)-2-(二苄胺基)-4-甲基戊酸苄酯,进而在碱性条件下与乙腈发生亲核取代反应得(S)-4-(二苄胺基)-6-甲基-3-氧代庚腈,再经硼氢化钠选择性还原羰基得(3S,4S)-4-(二苄胺基)-3-羟基-6-甲基庚腈,用双氧水氧化得(3S,4S)-4-(二苄胺基)-3-羟基-6-甲基庚酸,最后在Pd(OH)2/C-H2作用下脱掉苄基得到(3S,4S)-4-氨基-3-羟基-6-甲基庚酸,即(3S,4S)-statine。整个合成路线总产率为33.6%。 相似文献
46.
The effect of magnetic field strength and orientation on two types of electromagnetically influenced turbulent flows was studied numerically under the Reynolds averaged Navier–Stokes (RANS) framework. Previous work (Wilson et al., 2014) used an electromagnetically extended linear eddy-viscosity model, whilst the current paper focuses on the performance of a more advanced Reynolds stress transport type model both with and without electromagnetic modifications proposed by Kenjereš et al. (2004). First, a fully-developed 2D channel flow is considered with a magnetic field imposed in either the wall-normal or streamwise direction. Both forms of the RSM gave good agreement with the DNS data for the wall-normal magnetic field across the range of Hartmann numbers with the additional electromagnetic terms providing a small, but noticeable, difference. For the streamwise magnetic field, where electromagnetic influence is only through the turbulence, the electromagnetically extended RSM performed well at moderate Hartmann numbers but returned laminar flow at the highest Hartmann number considered, contrary to the DNS. The RSM results were, however, significantly better than the previous eddy-viscosity model predictions. The second case is that of unsteady 3D Rayleigh–Bénard convection with a magnetic field imposed in either a horizontal or vertical direction. Results revealed that a significant reorganization of the flow structures is predicted to occur. For a vertically oriented magnetic field, the plume structures increase in number and become thinner and elongated along the magnetic field lines, leading to an increase in thermal mixing within the core in agreement with Hanjalić and Kenjereš (2000). With a horizontal magnetic field, the structures become two-dimensional and a striking realignment of the roll cells’ axes with the magnetic field lines occurs. The results demonstrate the capability of the Reynolds stress transport approach in modelling MHD flows that are relevant to industry and offer potential for those wishing to control levels of turbulence, heat transfer or concentration without recourse to mechanical means. 相似文献
47.
Intermolecular Stetter reaction of aromatic aldehydes with (E)-(2-nitrovinyl)cyclohexane catalyzed by thiazolium A has been developed. The reaction rate and efficiency are profoundly impacted by the presence of thiourea B. The reaction affords moderate to good yields of the Stetter product. Some factors influencing yield were discussed. 相似文献
48.
《Current Applied Physics》2015,15(11):1421-1427
The effect of negative electric field on spin-dependent tunneling in double barrier heterostructures of III–V semiconductor is theoretically investigated. The transfer matrix approach is used by considering Dresselhaus and induced-Rashba effect to calculate the barrier transparency and polarization efficiency. Cent percent polarization efficiency can be achieved for the negative electric field by increasing the width of the potential barrier. The separation between spin-up and spin-down resonances are evaluated. The separation between spin resonances and tunneling lifetime of electrons are observed for various negative electric fields as well as for various barrier widths. The linear variation of spin separation and tunneling lifetime of electrons are observed as a function of negative electric field. 相似文献
49.
Theoretical investigations on the insertion reaction mechanisms of three- membered-ring silylenoid H2 Si Li F with GeH 3R(R = F, OH, NH2) have been systematically carried out by combined density functional theory(DFT) and ab initio quantum chemical calculations. The geometries of all stationary points for these reactions were optimized using the B3 LYP method and then the QCISD method was used to calculate the single-point energies. The calculated results indicate that, there are one precursor complex(Q), one transition state(TS), and one intermediate(IM) which connect the reactants and the products along the potential energy surface. The insertion reactions of three-membered-ring silylenoid with Ge H3 R proceed in a concerted manner, forming H2RSi-Ge H3 and Li F. The calculated potential energy barriers of the three reactions are 29.17, 30.90, and 54.07 k J/mol, and the reaction energies for the three reactions are –127.05, –116.91, and –103.31 k J/mol, respectively. The insertion reactions in solvents are similar to those in vacuum. Under the same situation, the insertion reactions should occur easily in the following order: GeH 3-F GeH 3-OH GeH 3-NH2. The elucidations of the mechanism of these insertion reactions provided a new mode of silicon-germanium bond formation. 相似文献
50.